Review

  • Journal of Nuclear Fuel Cycle and Waste Technology
  • Volume 2(4); 2004
  • Article

Journal of Nuclear Fuel Cycle and Waste Technology 2004;2(4):231-238. Published online: Dec, 30, 2004

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Determination of major and minor elements in low and medium level radioactive wastes using closed-vessel microwave acid digestion

  • Jeong-Jin Lee ; Hyung-Yeal Pyo ; Jong-Seon Jeon ; Chang-Heon Lee ; Kwang-Yong Jee and Pyung-Kook Ji
Abstract

The conditions are obtained for the decomposition of solid radioactive wastes, including ion exchange resin, zeolite, charcoal, and sludge from nuclear power plant. In the process of decomposing the radioactive wastes was used the microwave acid digestion method with mixed acid. The solution after acid digestion by the following method was colorless and transparent. Each solution was analyzed with ICP-AES and AAS and the recovery yield for 5 different elements added into the simulated radioactive wastes were over 94 %. The elemental analysis of destructive low and medium level radioactive wastes by the proposed microwave acid digestion conditions concerning the chemical characteristics of each radioactive waste are expected to be useful basic data for development of optimal glass formulation.

Keywords

Solid radioactive wastes,Microwave acid digestion,Inductively coupled plasma atomic emission spectrometry,Pre-treatment,Vitrification technology